Az összes toxikuselem és nehézfém meghatározása ICP-MS módszerrel

Data provider

Budapest University of Technology and Economics, Department of Applied Biotechnology and Food Science, Environmental Microbiology and Biotechnology Group

Organisation/Data provider's nameBudapest University of Technology and Economics, Department of Applied Biotechnology and Food Science, Environmental Microbiology and Biotechnology Group
Name of contact
Dr. Molnár Mónika, Dr. Feigl Viktória
Contact details
Telephone/fax
+36-1-4632347
E-mail
mmolnar@mail.bme.hu
vfeigl@mail.bme.hu
Website
http://envirotox.hu
Compulsory sheet
Method Hungarian nameAz összes toxikuselem és nehézfém meghatározása ICP-MS módszerrel
Method name
Analysis of toxic elements and heavy metals with ICP-MS
Stage of development
after application
Patent number
MSZ EN ISO 17294-2:2005
Contaminants
Chemical substance group|Typically treated chemical substance
  • Metals, semi-metals and their compounds
  • arsenic
Description of the measurement technique
Detection limit
0.01 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Metals, semi-metals and their compounds
  • aluminium
Description of the measurement technique
Detection limit
0.01 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Metals, semi-metals and their compounds
  • cadmium
Description of the measurement technique
Detection limit
0.01 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Metals, semi-metals and their compounds
  • chromium
Other parameter or substance
összes króm-tartalom
Description of the measurement technique
Detection limit
0.01 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Metals, semi-metals and their compounds
  • copper
Description of the measurement technique
Detection limit
0.01 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Metals, semi-metals and their compounds
  • mercury
Description of the measurement technique
Detection limit
0.01 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Metals, semi-metals and their compounds
  • nickel
Description of the measurement technique
Detection limit
0.01 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Metals, semi-metals and their compounds
  • lead
Description of the measurement technique
Detection limit
0.01 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Metals, semi-metals and their compounds
  • tin
Description of the measurement technique
Detection limit
0.01 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Metals, semi-metals and their compounds
  • zinc
Description of the measurement technique
Detection limit
0.01 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Metals, semi-metals and their compounds
Other parameter or substance
foszfor
Description of the measurement technique
Detection limit
0.01 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Metals, semi-metals and their compounds
Other parameter or substance
kén
Description of the measurement technique
Detection limit
0.01 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Metals, semi-metals and their compounds
  • iron
Description of the measurement technique
Detection limit
1 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Not a chemical substance
Other parameter or substance
kalcium
Description of the measurement technique
Detection limit
1 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Not a chemical substance
Other parameter or substance
nátrium
Description of the measurement technique
Detection limit
1 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Chemical substance group|Typically treated chemical substance
  • Not a chemical substance
Other parameter or substance
magnézium
Description of the measurement technique
Detection limit
1 µg/l
Accuracy (%)
10.00
Reproducibility (%)
10.00
Deviation (%)
10.00
Selectivity
selective
Feasibility of the method
Method type
measurement/analytical method
Place of application
In laboratory
Application areas of the method
Identification of the contaminant
Contaminant characterisationin in environmental element/phase/sample
Contaminant characterisationin in extract
General characterisation of surface water
Characterisation of water ecosystem
Application possiblities of the method
Environmental monitoring
Screening of contaminated environment
Preliminary assessment of contaminated environment
Detailed assessment of contaminated environment
Monitoring of contaminated environment
Epidemiological investigation
Technology monitoring
Postmonitoring
Environmental element/phase the method may be applied to
Saturated soil
Unsaturated (whole) soil
Pore water
Subsurface water
Surface water
Surface water sediment
Leachate
Implementation conditions
Instrument/equipment needed to perform the measurement
ICP-MS (induktív csatolású plazmaégő - tömegspektrométer)
Standard materials for the test
Sc, Rh, Lu belső standardok
Reagents/materials for the test
argon gáz
How many samples are needed
1 gramm, 20 ml
Data processing level
data collection, recording, evaluation by software
Necessary qualification
higher education (chemist, chemical eng., biologist, bioeng, environmental eng, microbiologist, agroeng)
Type of laboratory
general analytical laboratory
Implementation costs
Purchase price of the equipment
40.000 - 200.000 Euro
Estimated equipment cost
40.000 - 200.000 Euro
Labour cost/measurement
2 - 4 Euro
Total cost/measurement
20 - 40 Euro
Innovation, main features
Brief concise description explaining the innovation

Szabványosított multielemes módszer Induktív csatolású plazma és tömegspektrométer felhasználásával. Az induktíven csatolt plazma ionokat képez a fémekből, melyet a tömegspektrométer, mint detektor mutat ki.
A módszerhez kapcsolódó további szabványok:
MSZ 21470-50:1998
MSZ 1484-3:1998
EPA 6020 A
MSZ 1484-3:2006

Typical (recommended) application of the method

Ez a legelterjedtebb környezetanalitikai módszer szervetlen mikroszennyezőanyagok kimutatására és mennyiségi meghatározására. Alkalmas felszíni és felszín alatti vizek, talaj, üledék, szennyvíziszap, hulladék, élelmiszer, vagy bármilyen bányászati, ipari vagy mezőgazdasági termék, műtrágya, növényvédőszer fémtartalmának kimutatására, ppm−ppb tartományban. Izotóp-speciációra is használható.

Detailed Protocol

Talaj, üledék, egyéb szilárd minták esetében mintaelőkészítés (lásd például: királyvizes roncsolás összes toxikuselem és nehézfém-tartalom meghatározásához), talajvíz, ivóvíz és felszín alatti víz esetén nem szükséges a mintaelőkészítés, majd műszeres mérés.

SWOT (evalaution based on scores)
Costs
2-high
Time requirement
3-medium
Workload requirement
3-medium
Equipment, apparata requirement
1-very high
Qualified labour
3-medium
Environmental risk and workplace risks
3-medium
Environmental reality
4-good
Adequate accuracy
4-good
Reproducibility
4-good
Cost efficiency
3-average
Feasibility
4-good
Availability
2-weak
Well known
4-good
SWOT (evaluation in words)
Strengths

Szimultán multielemes módszer, közel 70 elem meghatározására alkalmas, 10 ppb-s kimutatási határral.
A berendezés működése közben nem igényel állandó felügyeletet.

Weaknesses

Drága berendezés és üzemeltetés, főként a méréshez szükséges Argon gáz miatt.

Possibilities

Kapcsolt technikák alkalmazásával a módszer alkalmazási lehetőségei jól variálhatók: LC, IC, GC. LC vagy IC-val kapcsoltan a különbözőféleképpen oxidált formák szétválaszthatóak (pl.: Arzén különbözőféleképpen oxidált formái).

Threats

A szervízhálózat Magyarországon fejletlen.

Other information, references
Webpage references and DEMO reports

LIFE SUMANAS Sustainable Management and Treatment of Arsenit Bearing Ground Water in Southern Hungary
Projekt száma: LIFE05ENV/000418

Publications

MSZ 21470-50:1998

Completed applications
Location of the application, country
Magyarország
Location of the application, town and/or region
Makó
Year of application
2008
Application areas
Contaminant characterisationin in environmental element/phase/sample
General characterisation of surface water
Characterisation of the effect of technological interventions
Environmental element the method was applied to
Environmental monitoring
Preliminary assessment of contaminated environment
Technology monitoring
Postmonitoring
Environmental scenario the method was applied to
Water habitat: sediment exposed to threat by polluted surface water
Terrestial habitat: groundwater exposed to threat by polluted soil
Environmental element/phase the method was applied to
Subsurface water
Contaminant the method was applied to
arsenic
Lessons learned

Az ICP-MS berendezést ebben a progjektben HPLC-vel kapcsoltan alkalmazták, mely lehetővé tette az As különböző oxidációs fokú formáinak elválasztását, mely egy Makón alkalmazott talajvíz tisztítási technológia előrehaladását monitorozta.

Location of the application, country
Magyarország
Location of the application, town and/or region
Gyöngyösoroszi
Year of application
2006
Application areas
Characterisation of the interaction between soil and pollutant
Environmental element the method was applied to
Environmental monitoring
Preliminary assessment of contaminated environment
Monitoring of contaminated environment
Technology monitoring
Environmental element/phase the method was applied to
Leachate
Contaminant the method was applied to
arsenic
zinc
cadmium
chromium
lead
copper
Lessons learned

A gyöngyösorosziból származó mintáknak magas toxikus elem tartalma miatt az előkészített mintákat hígítani kellett, ami egy szokványos csurgalékvíznél nagyon ritkán fordul elő, még akkor is, ha szennyezett területről származik.

Adatlap tulajdonságai
Datasheet id (original)
16
Creator
Hajdu Csilla
Status
Verified
Adatlap típusaPhysico-chemical assessment methods
Létrehozás
Módosítás