Sugar factory lime

Budapest University of Technology and Economics, Department of Applied Biotechnology and Food Science, Environmental Microbiology and Biotechnology Group

Organisation/Data provider's nameBudapest University of Technology and Economics, Department of Applied Biotechnology and Food Science, Environmental Microbiology and Biotechnology Group
Name of contact
Dr. Molnár Mónika, Dr. Feigl Viktória
Telephone/fax
+36-1-4632347
Name
Magyar Cukor Zrt. - Sugar factory in Kaposvár
Town/place
Kaposvár
Street, No.
Pécsi utca 10-13.
Postal code
7400
Telephone/fax
Tel: 36-82-505-303 Fax: 36-82-505-301
Connection with the waste or by-product
Producer
Denomination of the waste or by-productSugar factory lime
Denomination of the waste or by-product in English
Sugar factory lime
Type of the waste or by-product data-sheet
General characterization
Functional characterisation
Non-hazardous waste from food industry
EWC code of waste
  • 02 WASTES FROM AGRICULTURE, HORTICULTURE, AQUACULTURE, FORESTRY, HUNTING AND FISHING, FOOD PREPARATION AND PROCESSING
  • 02 04 wastes from sugar processing
  • 02 04 02 off-specification calcium carbonate
Consistency of the waste or by-product
Sludge (sludgy), pasta
Description of the waste generating technology

After reception at the processing plant, the beet roots are washed, mechanically sliced into thin strips called cossettes, and passed to a machine called a diffuser to extract the sugar content into a water solution. During diffusion, a portion of the sucrose breaks down into invert sugars. Carbonatation is a procedure which removes impurities from raw juice before it undergoes crystallization. First, the juice is mixed with hot milk of lime (a suspension of calcium hydroxide in water). This treatment precipitates a number of impurities, including multivalent anions such as sulfate, phosphate, citrate and oxalate, which precipitate as their calcium salts and large organic molecules such as proteins, saponins and pectins, which aggregate in the presence of multivalent cations. In addition, the alkaline conditions convert the simple sugars, glucose and fructose, along with the amino acid glutamine, to chemically stable carboxylic acids. carbon dioxide is bubbled through the alkaline sugar solution, precipitating the lime as calcium carbonate (chalk). The thin juice is concentrated via multiple-effect evaporation to make a thick juice, roughly 60% sucrose by weight and similar in appearance to pancake syrup. Thick juice is fed to the crystallizers.
http://en.wikipedia.org/wiki/Sugar_beet Processing

Is it a hazardous waste?
no
Generated annual tonnage
35 000 t
Characterisation of the waste as a chemical substance
Product
Chemical substance, Main group|Chemical substance, Subgroup
  • Other organic chemical substance
Other type of chemical substance
Organic matter
Is the contained chemical substance main component, component or contaminant of the waste or by-products / biochar?
Component
Concentration of the chemical in the waste or by-product / biochar
7.57 %
Chemical substance, Main group|Chemical substance, Subgroup
  • Other inorganic chemical compounds
  • nitrogen (total)
Is the contained chemical substance main component, component or contaminant of the waste or by-products / biochar?
Component
Concentration of the chemical in the waste or by-product / biochar
0.27 %
Chemical substance, Main group|Chemical substance, Subgroup
  • Other inorganic chemical compounds
  • phosphorus pentoxide
Is the contained chemical substance main component, component or contaminant of the waste or by-products / biochar?
Component
Concentration of the chemical in the waste or by-product / biochar
1.15 %
Chemical substance, Main group|Chemical substance, Subgroup
  • Other inorganic chemical compounds
  • calcium
Other type of chemical substance
CaO
Is the contained chemical substance main component, component or contaminant of the waste or by-products / biochar?
Component
Concentration of the chemical in the waste or by-product / biochar
31.73 %
Chemical substance, Main group|Chemical substance, Subgroup
  • Other inorganic chemical compounds
  • magnesium
Other type of chemical substance
MgO
Is the contained chemical substance main component, component or contaminant of the waste or by-products / biochar?
Component
Concentration of the chemical in the waste or by-product / biochar
1.27 %
Chemical substance, Main group|Chemical substance, Subgroup
  • Metals, semi-metals and their compounds
  • copper
Is the contained chemical substance main component, component or contaminant of the waste or by-products / biochar?
Component
Concentration of the chemical in the waste or by-product / biochar
13.87 mg/kg
Chemical substance, Main group|Chemical substance, Subgroup
  • Metals, semi-metals and their compounds
  • manganese
Is the contained chemical substance main component, component or contaminant of the waste or by-products / biochar?
Component
Concentration of the chemical in the waste or by-product / biochar
167.00 mg/kg
Chemical substance, Main group|Chemical substance, Subgroup
  • Metals, semi-metals and their compounds
  • iron
Is the contained chemical substance main component, component or contaminant of the waste or by-products / biochar?
Component
Concentration of the chemical in the waste or by-product / biochar
1946.00 mg/kg
Chemical substance, Main group|Chemical substance, Subgroup
  • Metals, semi-metals and their compounds
  • zinc
Is the contained chemical substance main component, component or contaminant of the waste or by-products / biochar?
Component
Concentration of the chemical in the waste or by-product / biochar
28.60 mg/kg
Chemical substance, Main group|Chemical substance, Subgroup
  • Metals, semi-metals and their compounds
  • lead
Is the contained chemical substance main component, component or contaminant of the waste or by-products / biochar?
Contaminant
Concentration of the chemical in the waste or by-product / biochar
2.59 mg/kg
Chemical substance, Main group|Chemical substance, Subgroup
  • Metals, semi-metals and their compounds
  • cadmium
Is the contained chemical substance main component, component or contaminant of the waste or by-products / biochar?
Contaminant
Concentration of the chemical in the waste or by-product / biochar
0.29 mg/kg
Chemical substance, Main group|Chemical substance, Subgroup
  • Metals, semi-metals and their compounds
  • chromium
Is the contained chemical substance main component, component or contaminant of the waste or by-products / biochar?
Contaminant
Concentration of the chemical in the waste or by-product / biochar
4.27 mg/kg
Chemical substance, Main group|Chemical substance, Subgroup
  • Metals, semi-metals and their compounds
  • nickel
Is the contained chemical substance main component, component or contaminant of the waste or by-products / biochar?
Contaminant
Concentration of the chemical in the waste or by-product / biochar
2.70 mg/kg
Chemical substance, Main group|Chemical substance, Subgroup
  • Metals, semi-metals and their compounds
  • arsenic
Is the contained chemical substance main component, component or contaminant of the waste or by-products / biochar?
Contaminant
Concentration of the chemical in the waste or by-product / biochar
1.33 mg/kg
Chemical substance, Main group|Chemical substance, Subgroup
  • Metals, semi-metals and their compounds
  • mercury
Concentration of the chemical in the waste or by-product / biochar
0.01 mg/kg
Name of the waste/by-product
Sugar factory lime
Components of the waste/by-product

Organic matter: 7,57%; N: 0,27%; P2O5: 1,15%; K2O: 0,11%; CaO: 31,73%; MgO: 1,27%; Na2O: 0,04%; Total carbon: 9,22%; Cu: 13,87 mg/kg; Mn: 167,00 mg/kg; Fe: 1946,00 mg/kg; Zn: 28,60 mg/kg; Pb: 2,59 mg/kg; Cd: 0,29 mg/kg; Cr: 4,27 mg/kg; Ni: 2,70 mg/kg; As: 1,33 mg/kg; Hg: 0,01 mg/kg

pH
11
Dry matter content (%)
65
Moisture content (%)
35
Density (g/cm3)
1.1
Ignition loss (LOI) (%)
45
Organic content (%)
12
C/N ratio
16
Total Organic Carbon (mg/l)
9000
Homogeneity
Homogeneous
Pozzolan activity
no
Is this waste or by-product being utilised?
Yes
Utilisation

It is suitable for degraded and acidic soils. It is a good alternative P and N source.

References on utilisation

Mosen A. Beet-sugar handbook. John Wiley and Sons, 2006.;

Burcky, K., Marlander, B., 2000. Investigations on the nutrient content of carbonation lime during storage in the field. Zuckerindustrie 125 (3), 169–174.;

Wasner, J., Liebhard, P., Eigner, H., 2001. Application of carbonation lime on high ph soils in the pannonian region of austria. Zuckerindustrie 126 (3), 194–201.

Hazard characteristics
Not classified
Corrosive (korrozív, H8)
Measured harmful effects
Yes
If harmful effect was measured, please, specify what was measured, which method was used, who did the measurement, and what was the result

There is no harmful effect for the environment. The corrosive property can be coordinated by using safety devices.

Suspected harmful effects

The concentration of toxic metals is under the limit value.
It is corrosive (ph=11).

Would it be suitable for soil reclamation in general?
Yes
Justification, references

It is used as natural soil improving amendment.
Paleckienė, R., Sviklas, A.M., ©link¹ienė, R.( 2007) The Role of Sugar Factory Lime on Compound Fertilizer Properties, Polish Journal of Environmental Studies 16(3), pp. 423-426.
http://www.okogarancia.hu/letoltesek/mezogazdasag/tragya-taj
http://www.diva-portal.org/smash/get/diva2:411542/FULLTEXT01.pdf
http://www.sbreb.org/research/soil/soil11/CropAvailabilityFactoryLime.p…
http://www.crystalsugar.com/agronomy/gold/fact/lime.pdf

Would it supply nitrogen, phosphorous and/or potassium to the soil?
Yes
Justification, references

It is suitable for P amendment.
http://www.sbreb.org/research/soil/soil11/CropAvailabilityFactoryLime.p…
Paleckienė, R., Sviklas, A.M., ©link¹ienė, R.( 2007) The Role of Sugar Factory Lime on Compound Fertilizer Properties, Polish Journal of Environmental Studies 16(3), pp. 423-426.

Would it supply mesoelements (Ca, Cl, Fe, Mg, Na, S, Si) to the soil?
Yes
Justification, references

It is suitable for Ca and Mg amendment.

Paleckienė, R., Sviklas, A.M., ©link¹ienė, R.( 2007) The Role of Sugar Factory Lime on Compound Fertilizer Properties, Polish Journal of Environmental Studies 16(3), pp. 423-426.http://www.okogarancia.hu/letoltesek/mezogazdasag/tragya-taj

Would it supply microelements (B, Co, Cu, Mn, Mo, Zn, V) to the soil?
No
Justification, references

Paleckienė, R., Sviklas, A.M., ©link¹ienė, R.( 2007) The Role of Sugar Factory Lime on Compound Fertilizer Properties, Polish Journal of Environmental Studies 16(3), pp. 423-426.

Would it provide sufficient amounts of special nutrients to the soil?
No
Would it increase the humus/organic matter content of the soil?
No
Would it suffice as a main component of growing media?
No
Would it suffice as an additive to growing media?
No information
Would it improve the structure of compacted soil and/or contribute to soil crumb formation of poorly structured soils?
No information
Would it be suitable for physical stabilisation and/or texture improvement of loose, quagmire soils?
No information
Would it be suitable for amending sandy soils?
No information
Would it be suitable for erosion prevention?
No information
Would it be suitable for amending acidic soils?
Yes
Justification, references

Because of its pH=11.
Paleckienė, R., Sviklas, A.M., ©link¹ienė, R.( 2007) The Role of Sugar Factory Lime on Compound Fertilizer Properties, Polish Journal of Environmental Studies 16(3), pp. 423-426.

Pedro González-Fernándeza, Rafaela Ordóñez-Fernándeza, Ignacio Mariscal-Sanchob, Rafael Espejo-Serranob (2012) Economics of applications of sugar factory lime refuse in Mediterranean Ultisols, Archives of Agronomy and Soil Science 58(1). pp. 185-189.
http://www.crystalsugar.com/agronomy/gold/fact/lime.pdf

Would it be suitable for amending saline and sodic soils?
No
Would it reduce the mobility and availability of the contaminants?
No information
Would it intensify the mobility, availability of the contaminants?
No information
Would it intensify physical, chemical, and/or biological degradation and decomposition of contaminants?
No information
Would it be suitable for production of geotechnical elements?
No information
Risks associated with potential utilisation in soil

When it is applied to soil, the amount should be determined calculating with the soil own heavy metal concentration. The alkalinity is not problematic up until 20%, it sholud be calculated based on the soil own pH.
Paleckienė, R., Sviklas, A.M., ©link¹ienė, R.( 2007) The Role of Sugar Factory Lime on Compound Fertilizer Properties, Polish Journal of Environmental Studies 16(3), pp. 423-426.
http://www.diva-portal.org/smash/get/diva2:411542/FULLTEXT01.pdf

Datasheet id (original)
1326
Creator
Fekete-Kertész Ildikó
Status
Verified
Adatlap típusaWaste / by-product survey
Létrehozás
Módosítás